Resistance Characteristic
Electrical resistance decreases as the ambient or internal temperature of a conductive material rises. This negative temperature coefficient is a defining feature of semiconductors and certain ceramic thermistors. In contrast, most metals exhibit an increase in resistance when heated.
Charge Mobility
Thermal energy releases more charge carriers into the conduction band as the temperature climbs. The higher density of available electrons or holes overcomes the effect of increased lattice scattering, which is why a material with a negative temperature coefficient becomes more conductive. This behaviour allows for the creation of sensitive temperature sensors.
Sensor Calibration
Resistance follows a non-linear exponential curve. Manufacturers provide a lookup table or a mathematical model for each negative temperature coefficient device.
Operational Stability
Self-heating occurs when the current passing through the component generates enough heat to lower the resistance further. This feedback loop can lead to thermal runaway if the circuit design does not include current-limiting elements. Engineers use the B-parameter to characterize the sensitivity of the material over a specific range.
Verification of the coefficient involves measuring the resistance at several stable temperature points in a controlled bath. This data ensures that the sensor provides accurate readings across its intended environmental envelope.