Electromagnetic Measurement
Dissolved ion concentration in aqueous solutions can be determined without direct electrical contact between the sensor electrodes and the fluid. This measurement technique is called inductive conductivity, which utilizes two closely coupled toroidal coils to induce and measure an electrical current in the surrounding medium. The method is applicable in highly saline or fouling-prone environments where traditional electrode sensors would quickly degrade.
Toroidal Interaction
The sensor housing contains a primary coil that is driven by an alternating voltage to generate an oscillating magnetic field. This magnetic field forces the ions in the surrounding water to move, creating a closed current loop through the center of the toroid. A secondary coil within the housing detects this induced ionic current and generates an output signal proportional to the solution strength.
This design avoids the polarization errors that typically affect direct-contact electrodes.
Sensing Boundary
Sensing accuracy depends on the volume of fluid surrounding the sensor head. If the sensor is placed too close to a non-conductive boundary, the induced current loop is compressed, resulting in an artificially low reading. This installation effect must be managed by maintaining the minimum clearance specified by the manufacturer.
Calibration Reference
Metrological labs verify these instruments using standard potassium chloride solutions of known concentration and temperature. Since temperature has a large effect on ionic mobility, the sensor must perform simultaneous temperature measurement to calculate the corrected conductivity. A sensor that deviates from the reference standard beyond the specified tolerance must be adjusted or recalibrated.
This verification confirms that the electromagnetic coils are operating within their design specifications.